团队成员
   
 
          徐    刚 
   
            徐雪青
   
                肖秀娣
   
            朱艳青
   
            钟柳文
   
                李柱苓
 团队成员                >  研究室副主任        >  首页
 

 
 

        研究室副主任:徐雪青

研究员  博士生导师 

博士

xuxq@ms.giec.ac.cn

   
 
 

       主要从事光电材料与器件研究,包括第三代太阳电池、量子点材料与发光二极管器件、以及纳米光电功能薄膜与器件(纳米WO3致变色薄膜、减反射膜、透明导电膜、太阳光谱选择性吸收涂层等),成功制备多种高效无镉量子点材料与发光二极管器件,并在新型太阳电池载流子输运、界面电荷转移、及电子复合动力学研究方面取得了系列研究成果,钙钛矿太阳电池效率达到世界先进水平。

       作为主持人或主要参加者承担国家“863”、国家基金、省市科技攻关等科研项目近30项,在国内外重要学术刊物(Energy & Environmental Science, ACS Nano, J. Phys. Chem. C,ACS Appl. Mater. Interface,J. Mater. Chem. A, Solar Energy materials & solar cells ,Journal of Applied Physics)上发表高质量学术论文126余篇,其中SCI/EI收录88篇,SCI总引频次2000次,获得美国授权发明专利申请1件,国家发明专利授权15件。

 

主要研究方向:

1. 纳米光电功能材料

2. 钙钛矿太阳电池

3. 量子点材料与发光二极管

4. 太阳能利用光电功能薄膜与器件

 

主要学习与工作经历:

2011.12-至今  研究员,中国科学院广州能源研究所太阳能研究室;

2003.10-2011.11  副研究员,中国科学院广州能源研究所太阳能研究室,2006年起任副主任;

1998.08 - 2003.09  助理研究员,中国科学院广州能源研究所太阳能研究室;

1994.05 - 1998.07  研究实习员,中国科学院广州能源研究所;

 

2011.01-2011.02  高级副研究员,香港城市大学材料与应用物理系Andrey Rogach教授研究小组;

2010.01 - 2010.07  访问学者,西班牙海梅一世大学(Universitat of Jaume I)应用物理系;

2008.11 - 2009.04  访问学者,西班牙海梅一世大学(Universitat of Jaume I)应用物理系Juan Bisquert 研究小组;

2004.07 - 2004.10  访问学者,德国Fraunhofer不莱梅应用材料研究所;

 

2002.09 - 2005.06  中山大学化学与化学工程学院,获理学博士学位;

1991.09 - 1994.04  华南理工大学轻工食品学院,获工学硕士学位;

1987.09 - 1991.07  华南理工大学轻工食品学院,获工学学士学位;

 

主要承担项目:

1. 国家自然科学基金面上项目(2013.01–2016.12)

   基于无机有机复合空穴导体的全固态量子点敏化太阳电池的构建及其载流子动力学研究(21273241)   76万

2. 广州市重点领域研发项目(2020.04-2023.03)

   新型发光二极管材料及其显示应用关键技术研究(202007020004)  150万

3. 广东省协同创新与平台环境建设专项资金项目(2018.12–2021.11)

   柔性低成本有机-无机钙钛矿杂合物太阳电池的研究(2018A050506067)  50万

4. 广东省重大专项(2015.03-2017.02)

   多功能智能型建筑隔热涂料的研发与小规模生产(2013A011401010)  200万

5. 广州市协同创新重大专项(2017.05-2021.04)

    环保型量子点及其印刷显示LED研究(201704030069)   200万

6. 广东省协同创新与平台环境建设专项资金项目(2015.01–2016.12)

    高效且性能稳定有机-无机钙钛矿杂合物太阳电池的研究(2014A050503051)  50万

7. 广东省自然科学基金项目(2015.08–2018.08)

    有机-无机三元合金钙钛矿杂化物薄膜的设计制备及其在太阳电池中的应用研究(2015A030310501)  10万

 

代表性论文、论著:

1. 沈辉,刘勇,徐雪青编著,《纳米材料与太阳能利用》,化学工业出版社,北京,2012

 

1.  Cong Shen, Yanqing Zhu, Zixiao Li, Jingling Li, Hong Tao, Jianhua Zou, Xueqing Xu* and Gang Xu, Highly luminescent InP–In(Zn)P/ZnSe/ZnS core/shell/shell colloidal quantum dots with tunable emissions synthesized based on growth-doping, Journal of Materials Chemistry C 2021, 9(30):9599-9609.

2.  Marimuthu, T.; Yuvakkumar, R.; Senthil Kumar, P.; Ravi, G.; Xu, X.; Xu, G.; Velauthapillai, D., Pristine and cobalt doped copper sulfide microsphere particles for seawater splitting. International Journal of Hydrogen Energy 2021.

3.  Marimuthu, T.; Yuvakkumar, R.; Kumar, P. S.; Vo, D.-V. N.; Xu, X.; Xu, G., Two-dimensional hybrid perovskite solar cells: a review. Environmental Chemistry Letters 2021.

4.  Bi, Z. N.; Zhang, S. H.; Thandapani, M.; Zhu, Y. Q.; Zheng, Y. P.; Liem, N. Q.; Xiao, X. D.; Xu, G.; Guerrero, A.; Xu, X. Q., High Shunt Resistance SnO2-PbO Electron Transport Layer for Perovskite Solar Cells Used in Low Lighting Applications. Adv. Sustain. Syst. 2021, 5 (11), 7.

5.  Marimuthu, T.; Yuvakkumar, R.; Senthil Kumar, P.; Ravi, G.; Xu, X.; Velauthapillai, D.; N. Vo, D. V., Cost effective and facile low temperature hydrothermal fabrication of Cu2S thin films for hydrogen evolution reaction in seawater splitting. International Journal of Hydrogen Energy 2021.

6.  Liu, C.; Liu, R.; Bi, Z. E.; Yu, Y.; Xu, G.; Hou, H. M.; Wu, Q. F.; Yu, H.; Xu, X. Q., Multiple-Ring Aromatic Spacer Cation Tailored Interlayer Interaction for Efficient and Air-Stable Ruddlesden-Popper Perovskite Solar Cells. Sol. RRL 2021, 5 (10), 8.

7.  Wang, J. X.; Liu, Y. B.; Xiao, X. D.; Bi, Z. N.; Lu, Y.; Sheng, G. Z.; Cai, X. S.; Zhu, Y. Q.; Xu, X. Q.; Xu, G., An efficient post-treatment strategy with acetylacetone for low temperature CsPbI2Br solar cells. Sol. Energy 2021, 216, 7-13.

8.  Chen, J. N.; Zhang, J. K.; Huang, C. W.; Bi, Z. N.; Xu, X. Q.; Yu, H. Z., SnO2/2D-Bi2O2Se new hybrid electron transporting layer for efficient and stable perovskite solar cells. Chem. Eng. J. 2021, 410, 11.

9.  Deng, B.; Zhu, Y. Q.; Li, J. L.; Chen, X.; He, K.; Yang, J.; Qin, K. L.; Bi, Z. N.; Xiao, X. D.; Chen, S. J.; Xu, X. Q.; Xu, G., Low temperature synthesis of highly bright green emission CuInS2/ZnS quantum dots and its application in light-emitting diodes. J. Alloy. Compd. 2021, 851, 10.

10.  Zhang, X. Q.; Li, J. L.; Bi, Z. N.; He, K.; Xu, X. Q.; Xiao, X. D.; Zhu, Y. Q.; Zhan, Y. J.; Zhong, L. W.; Xu, G.; Yu, H. Z., Stable and efficient air-processed perovskite solar cells employing low-temperature processed compact In2O3 thin films as electron transport materials. J. Alloy. Compd. 2020, 836, 9.

11.  Shen, C.; Zhu, Y. Q.; Xiao, X. D.; Xu, X. Q.; Chen, X. L.; Xu, G., Economical Salt-Resistant Superhydrophobic Photothermal Membrane for Highly Efficient and Stable Solar Desalination. ACS Appl. Mater. Interfaces 2020, 12 (31), 35142-35151.

12.  Shen, C.; Zhu, Y. Q.; Shi, W. N.; He, K.; Xiao, X. D.; Xu, X. Q.; Shi, J. F.; Xu, G., Mechanically stable superhydrophobic surface on cement-based materials. Chem. Phys. 2020, 538, 7.

13.  He, K.; Shen, C.; Zhu, Y. Q.; Chen, X. L.; Bi, Z. N.; Marimuthu, T.; Xu, G.; Xu, X. Q., Stable Luminescent CsPbI3 Quantum Dots Passivated by (3-Aminopropyl)triethoxysilane. Langmuir 2020, 36 (34), 10210-10217.

14.  He, K.; Zhu, Y. Q.; Bi, Z. N.; Chen, X. L.; Xiao, X. D.; Xu, G.; Xu, X. Q., Highly luminescent CsPbI3 quantum dots and their fast anion exchange at oil/water interface. Chem. Phys. Lett. 2020, 741, 6.

15.  Chen, J. Y.; Bi, Z. N.; Xu, X. Q.; Yu, H. Z., The low temperature solution-processable SnO2 modified by Bi2O2S as an efficient electron transport layer for perovskite solar cells. Electrochim. Acta 2020, 330, 11.

16.  Liu, H. S.; Xiao, X. D.; Bi, Z. N.; Wang, J. X.; Liu, Y. B.; Zhu, Y. Q.; Xu, X. Q.; Xu, G., A facile method to improve the stability and efficiency of CsPbI2Br perovskite solar cells prepared at low temperature. Sol. Energy 2020, 195, 544-551.

17.  Zhan, Y. J.; Lu, Y.; Xiao, X. D.; Wang, J. X.; Liu, Y. B.; Zhang, S. S.; Shen, C.; Xu, X. Q.; Xu, G., Tuning thermochromic performance of VOx based multilayer films by controlling annealing pressure. Ceram. Int. 2020, 46 (2), 2079-2085.

18.  Wang, K. L.; Liang, Z.; Li, J. L.; Xu, X. Q.; Cheng, X. L.; Jin, H.; Xu, D. H.; Xu, G., Formation and photoluminescence properties of colloidal ZnCuIn(SexS1-x)2/ZnS nanocrystals with gradient composition. J. Mater. Sci. 2019, 54 (3), 2037-2048. (SCI收录,影响因子:3.442, 二区)

19.  Liang, Z. R.; Bi, Z. N.; Gao, K.; Fu, Y. F.; Guan, P. Y.; Feng, X. L.; Chai, Z. S.; Xu, G.; Xu, X. Q*., Interface modification via Al2O3 with retarded charge recombinations for mesoscopic perovskite solar cells fabricated with spray deposition process in the air. Applied Surface Science 2019, 463, 939-946. (SCI收录,影响因子:5.155, 一区)

20.  Qin, K. L.; Li, J. L.; Zhu, Y. Q.; Xu, X. Q.; Xiao, X. D.; Deng, B.; Yang, J.; Bi, Z. N.; Chen, S. J.; Xu, G., Crystal Structure Control of ZnxCd1-xS Alloyed Nanocrystals and Structural Dependent Fluorescence Properties. Nano 2019, 14 (8): 1950098-1. (SCI收录,影响因子:1.293, 三区)

21.  Yang, J.; Li, J. L.; Zhu, Y. Q.; Xu, X. Q.; Xiao, X. D.; Deng, B.; Qin, K. L.; Bi, Z. N.; Chen, S. J.; Xu, G., Low-Temperature Synthesis of Highly Efficient, Deep-Red Zn-Cu-In-Se/ZnSe Fluorescence Quantum Dots. Nano 2019, 14 (6):1950070-1 (SCI收录,影响因子:1.293, 三区)

22.  Zuoneng Bi, Rodríguez-Martínez Xabier, Aranda Clara, Enrique Pascual San Jose, Alejandro R. Goñi, Mariano Campoy-Quiles*, Xueqing Xu*, Antonio Guerrero, Defect Tolerant Perovskite Solar Cells from Blade coated Non-Toxic Solvents, Journal of Materials Chemistry A, 2018, 6(39): 19085-19093  (SCI收录,影响因子:10.733, 一区)

23.  Li JL, Liang Z, Su Q, Jin H, Wang KL, Xu G, Xu XQ*, Small Molecule-Modified Hole Transport Layer Targeting Low Turn-On-Voltage, Bright, and Efficient Full-Color Quantum Dot Light Emitting Diodes, ACS Appl. Mater. Interfaces, 2018,10(4):3865-3873. (SCI收录,影响因子:8.456, 一区)

24.  Li JL, Guo QL, Jin H, Wang KL, Xu DH, Xu Y, Xu G, Xu XQ. Improved performance of quantum dot light emitting diode by modulating electron injection with yttrium-doped ZnO nanoparticles. Journal of Applied Physics 2017,122(13): 135501-135508 (SCI收录,影响因子:2.328, 二区)

25.  Jin H, Xu DH, Li JL, Wang KL, Bi ZN, Xu G, Xu XQ. Highly Solar-Reflective Litchis-Like Core-Shell HGM/TiO2 Microspheres Synthesized by Controllable Heterogeneous Precipitation Method. Nano 2017,12: 1750080-1750087(SCI收录,影响因子:1.293, 三区)

26.  Zhuoneng Bi, Zhurong Liang, Zhisheng Chai, Xueqing Xu*, Hu Jin, Dehua Xu, Jinling Li, Minhua Li, Gang Xu, Fast Preparation of Uniform Large Grain Size Perovskite Thin Film in Air Condition via Spray Deposition Method for High Efficient Planar Solar Cells, Solar Energy materials & solar cells, 2017, 162:16-20. (SCI收录,影响因子:6.019, 一区)

27.  Jinlin Li, Hu Jin, Keilai Wang, Dehui Xie, D Xu, Xueqing Xu*, Gang Xu. Low-temperature solution-processed MoOx as hole injection layer for efficient quantum dot lightemitting diodes. RSC Advances 2017, 7: 27464. (SCI收录,影响因子:3.108, 二区)

28.  Wang JX, Yu DS, Xu XQ, Shen HL. New insights into a first principle calculation and experimental study of SnPb-Ge ternary-metal perovskites for potential photovoltaic application. Materials Science in Semiconductor Processing 2017;68:159-64. (SCI收录,影响因子:2.722, 二区)

29.  Peng G, Ellis JE, Xu G, Xu X, Star A. In Situ Grown TiO2 Nanospindles Facilitate the Formation of Holey Reduced Graphene Oxide by Photodegradation. ACS Appl Mater Interfaces 2016;8:7403-10.

30.  Peng G, Wu S, Ellis JE, Xu X, Xu G, Yu C, et al. Single-walled carbon nanotubes templated CuO networks for gas sensing. Journal of Materials Chemistry C 2016;4.

31.  Jinlin Li, Hu Jin, Keilai Wang, Dehui Xie, D Xu, Xueqing Xu*, Gang Xu. High luminance of CuInS2-based yellow quantum dot light emitting diodes fabricated by all-solution processing. RSC Advances 2016;6:72462. (SCI收录,影响因子:3.7)

32.  Guiming Peng, Jiamin Wu, Suqin Wu, Xueqing Xu*, James E. Ellis, Gang Xu*, Alexander Star, and Di Gao, Perovskite solar cells based on bottom-fused TiO2 nanocones. Journal of Materials Chemistry A 2016, 4, (4), 1520-1530(SCI收录,影响因子:10.733)

33.  Junxia Wang, Jinlin Li, Xueqing Xu*, Zhuoneng Bi, Gang Xu, Honglie Shen. Promising photovoltaic application of multi-walled carbon nanotubes in perovskites solar cells for retarding recombination. RSC Advances, 2016, 6, 42413. (SCI收录,影响因子:3.7)

34.  Junxia Wang, Jinlin Li, Xueqing Xu*, Gang Xu, Honglie Shen. Enhanced photovoltaic performance with carbon nanotubes incorporating into hole transport materials for perovskite solar cells. Journal of Electronic Materials, 2016, 45:5127.(SCI)

35.  Junxia Wang, Xueqing Xu, and Zhurong Liang. "Comparison of the sensitized and heterojunction solar cells based on the Sn/Pb alloy perovskites." In International Photonics and OptoElectronics, JW3A.16. Wuhan: Optical Society of America, 2015. (EI)

36.  Zhurong Liang, Xueqing Xu, and Junxia Wang. "A Facile Spray Deposition Route for Uniform Perovskite Solar Cells Processed in Air." In International Photonics and OptoElectronics, JW3A.20. Wuhan: Optical Society of America, 2015. (EI)

37.  M. Lv, X. Dong, X. Fang, B. Lin, S. Zhang, X. Xu, J. Ding, N. Yuan, Improved photovoltaic performance in perovskite solar cells based on CH3NH3PbI3 films fabricated under controlled relative humidity, RSC Advances, 5 (2015) 93957-93963. (SCI收录,影响因子:3.7)

38.  Zhurong Liang, Shaohong Zhang, Xueqing Xu*, Nan Wang, Junxia Wang, Xin Wang, Zhuoneng Bi, Gang Xu, Ningyi Yuan and Jianning Ding. Large grain size perovskite thin film with dense structure for planar heterojunction solar cells via spray deposition under ambient condition, RSC Advances, 2015, 5, 60562 – 60569 (SCI收录,影响因子:3.7)

39.  Nan Wang, Zhurong Liang, Xin Wang, Xueqing Xu*, Jun Fang, Junxia Wang, Huafang Guo, CuInS2 Quantum Dot-Sensitized Solar Cells Fabricated via a Linker-Assisted Adsorption Approach,  Acta Phys. -Chim. Sin. 2015, 31 (7):1331-1337 (SCI收录)

40.  Xin Wang, Zhurong Liang, Xueqing Xu*, Nan Wang, Jun Fang, Junxia Wang, Gang Xu, A high efficient photoluminescence Zn-Cu-In-S /ZnS quantum dots with long lifetime, J. Alloy. Compd.,  2015, 640:134-140  (SCI收录,影响因子:3.0)

41.  Guiming Peng, Xueqing Xu*, and Gang Xu, Hybrid Organic-Inorganic Perovskites Open a New Era for Low-Cost, High Efficiency Solar Cells, Journal of Nanomaterials, 2015, Article ID 241853. (SCI收录)

42.  Ping An, Zhurong Liang, Xueqing Xu*, Xin Wang, Hu Jin, Nan Wang, Furong Zhu, Heating-up synthesis of pure phase kesterite Cu2ZnSnS4 nanocrystals using simple coordinating sulphur precursor, RSC Advances, 2015. 5: 6879-6885.(SCI收录,影响因子:3.7)

 

代表性专利:

1. 徐雪青,王军霞,梁柱荣,徐刚,一种吸收光谱可调钙钛矿结构有机-无机三元合金杂合物薄膜光阳极及其制备方法,发明专利,申请号:201510166025.3,申请日:2015年4月9日;专利号:ZL 201510166025.3,2017年5月24日授权

2. 徐雪青,王欣,梁柱荣,谢德辉,一种CuInS2/In2S3/ZnS双层核壳结构荧光量子点及其制备方法,发明专利,申请号:201510249711.7,申请日:2015年4月9日;专利号:201510249711.7,授权日:2016年6月29日

3. 徐雪青,成晓玲,高潘,谢德辉,靳虎,一种毫米通道式连续化制备系统,发明专利,专利号:ZL 201520692856x,授权日:2016年1月3日

4. 徐雪青,王欣,梁柱荣,谢德辉,一种CuInS2/In2S3/ZnS双层核壳结构荧光量子点及其制备方法,PCT专利,申请号:PCTCN2015087955

5. 徐雪青,梁柱荣,徐刚,一种衬底表面制备纳米银/锑掺杂氧化锡透明导电热反射涂层的方法,发明专利,申请号:201610240388.1,申请日:2016年4月18日;专利号:ZL 201610240388.1,2017年3月15日授权

6.徐雪青,符小艺,何新华,徐得华,徐刚,一种基于双层壳体相变控温微胶囊的热反射型外墙建筑隔热水性涂料及其制备方法,发明专利,申请号:2016105801170,申请日:2016年7月21日; 专利号:ZL 2016105801170,2017年6月23日授权

7.徐雪青,范玉容, 王毅, 梁柱荣,徐刚,一种陶瓷衬底表面太阳选择性吸收涂层及其制备方法,发明专利,申请号:201610240343.4,申请日:2016年4月18日;专利号:ZL 201610240343.4,2017年11月3日授权

8.徐雪青,高凯,毕卓能,徐刚,张晓清,一种有机无机杂化钙钛矿太阳电池及其制备方法,申请号:2017104936419,申请日:2017年6月26日

9.徐雪青,靳虎,徐得华,徐刚,一种氧化物中空微球的制备方法,申请号:201710379916.6,申请日:2017年5月25日

10. 徐雪青,李景灵,徐刚,一种基于掺钇氧化锌电子传输层的量子点发光二极管及其制备方法, 发明专利,申请号:201711341870.5,申请日:2017年12月14日;

11. 徐雪青,杨娟,徐刚,朱艳青,一种ZnCuInSe/ZnSe核壳结构荧光量子点及其制备方法,发明专利,申请号:2018107509627,申请日:2018年7月2日;

12. 徐雪青,邓兵,徐刚,朱艳青,一种CuInS2/ZnS/ZnS/ZnS多层核壳结构绿色荧光量子点及其制备方法,发明专利,申请号:2020103863677,申请日:2020.05.09;公开号:CN111662703A, 公开日:2020.09.15;

13. Xu Xueqing, Wan Xin, Xie Dehui, CuInS2/In2S3/ZnS Fluorescent Quantum Dot with Double-layer Core-shell Structure and Preparation Method Thereof. 专利号:US 10563123B2,2020年2月18日授权

14. 徐雪青,毕卓能,徐刚,一种基于多层梯度能带电子传输层的钙钛矿太阳电池,发明专利,申请号:202110743972X,申请日:2021.07.01

15. 徐雪青,徐刚,曹曙光,郑宇鹏,朱艳青,一种钙钛矿太阳能电池,发明专利,申请号:2021114371115,申请日:2021.11.29